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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Version 5.2 Revision Date 11.05.2015 Print Date 24.03.2016 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1
1.2
Product identifiers Product name
:
4-(Methylamino)phenol hemisulfate salt
Product Number Brand Index-No. REACH No.
: : : :
CAS-No.
:
320013 Aldrich 650-031-00-4 A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. 55-55-0
Relevant identified uses of the substance or mixture and uses advised against Identified uses
1.3
1.4
:
Laboratory chemicals, Manufacture of substances
Details of the supplier of the safety data sheet Company
:
Sigma-Aldrich Chemie BV Stationsplein 4 3331 LL ZWIJNDRECHT NETHERLANDS
Telephone Fax E-mail address
: : :
+31 78-620-5411 +31 78-620-5421
[email protected]
Emergency telephone number Emergency Phone #
112
SECTION 2: Hazards identification 2.1
Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Eye irritation (Category 2), H319 Skin sensitisation (Category 1), H317 Specific target organ toxicity - repeated exposure (Category 2), H373 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC N Dangerous for the R50/53, R36 environment R43 Xn Harmful R22, R48/22 For the full text of the R-phrases mentioned in this Section, see Section 16.
2.2
Label elements Labelling according Regulation (EC) No 1272/2008
Aldrich - 320013
Page 1 of 8
Pictogram Signal word
Warning
Hazard statement(s) H302 H317 H319 H373 H410
Harmful if swallowed. May cause an allergic skin reaction. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects.
Precautionary statement(s) P273 P280
Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Collect spillage. Dispose of contents/ container to an approved waste disposal plant.
P333 + P313 P337 + P313 P391 P501 Supplemental Hazard Statements 2.3
none
Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
SECTION 3: Composition/information on ingredients 3.1
Substances Formula Molecular weight CAS-No. EC-No. Index-No.
: : : : :
C7H9NO ยท 0.5H2SO4 172,19 g/mol 55-55-0 200-237-1 650-031-00-4
Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Bis(4-hydroxy-N-methylanilinium) sulphate CAS-No. 55-55-0 EC-No. 200-237-1 Index-No. 650-031-00-4
Acute Tox. 4; Eye Irrit. 2; Skin Sens. 1; STOT RE 2; Aquatic Acute 1; Aquatic Chronic 1; H302, H317, H319, H373, H410
Hazardous ingredients according to Directive 1999/45/EC Component Classification Bis(4-hydroxy-N-methylanilinium) sulphate CAS-No. 55-55-0 EC-No. 200-237-1 Index-No. 650-031-00-4
Xn, N, R22 - R43 - R48/22 R50/53 - R36
Concentration
