exam 10 2014 questions and answers

lOMoARcPSD|2663893 Exam 10 2014, questions and answers Chemistry B (University of South Africa) Distributing prohibit...

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lOMoARcPSD|2663893

Exam 10 2014, questions and answers

Chemistry B (University of South Africa)

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lOMoARcPSD|2663893

CHE1502 MAY/JUNE 2014 SECTION B MEMORANDUM Question 1 [10]

(a)

Draw the Newman projections of the different conformations of the following compound.

Identify the most stable and least stable conformation. (6)

(b)

Draw the structure of any secondary amine. Give the IUPAC name of the compound. (4) ANY STRUCTURE HAVING NITROGEN WITH 2 ALKYL/ARYL GROUPS AND ONE H ATTACHED TO IT

Question 2 [10]

(a)

Write the detailed mechanism of the following reaction: Cl Cl2 Cl

(6)

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2

Cl Cl

Cl

+ Cl

Cl Cl Cl

(b)

Cl

Draw the correct structure of 2-methylbutanoyl chloride.

CH3 CH3CH2CH

(c)

(2)

O C

Cl

Use curved arrows to show how the bond(s) break or form in the following process . (2)

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