D0782
Material Safety Data Sheet PROTECTIVE CLOTHING
RISK PHRASES
HAZARD WARNINGS
Toxic compound, do not ingest or inhale. Avoid all contact with this material. Irritating to skin, eyes, and the respiratory system. Light sensitive. Refrigerate.
Section I.
Chemical Product and Company Identification
Chemical Name
N,N-Dimethyl-1,4-phenylenediamine Sulfate
Catalog Number
Supplier
D0782
TCI America 9211 N. Harborgate St.
Synonym
Portland OR
4-Aminodimethylaniline Sulfate
1-800-423-8616
Chemical Formula
C 8 H 12 N 2 •H 2 SO
CAS Number
Section II.
4
In case of Emergency Call
536-47-0
Chemtrec® (800) 424-9300 (U.S.) (703) 527-3887 (International)
Composition and Information on Ingredients
Chemical Name
CAS Number
N,N-Dimethyl-1,4-phenylenediamine Sulfate
Percent (%) Not available.
Min.
536-47-0
Toxicology Data
TLV/PEL Rat LD Rat LDL
98.0%(Tit.)
50
(oral) 100 mg/kg
o
Mouse LD
Section III. Acute Health Effects
(oral) 75 mg/kg 50
(oral) 59 mg/kg
Hazards Identification T o x ic if in g e s t e d o r in h a le d .
A v o id p r o lo n g e d c o n t a c t w it h t h is m a t e r ia l.
O v e r e x p o s u r e m a y r e s u lt in s e r io u s illn e s s o r
death. Ir r it a t in g t o e y e s a n d s k in o n c o n t a c t . In h a la t io n c a u s e s ir r it a t io n o f t h e lu n g s a n d r e s p ir a t o r y s y s t e m . In f la m m a t io n o f t h e e y e is c h a r a c t e r iz e d b y r e d n e s s , w a t e r in g , a n d it c h in g .
S k in in f la m m a t io n is c h a r a c t e r iz e d b y it c h in g , s c a lin g ,
reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Chronic Health Effects
CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY : Not available. R e p e a t e d e x p o s u r e t o a n h ig h ly t o x ic m a t e r ia l m a y p r o d u c e g e n e r a l d e t e r io r a t io n o f h e a lt h b y a n a c c u m u la t io n in o n e or many human organs.
Section IV. Eye Contact
First Aid Measures C h e c k f o r a n d r e m o v e a n y c o n t a c t le n s e s . In c a s e o f c o n t a c t , im m e d ia t e ly f lu s h e y e s w it h p le n t y o f w a t e r f o r a t le a s t 1 5 minutes. Get medical attention.
Skin Contact
In c a s e o f c o n t a c t , im m e d ia t e ly f lu s h s k in w it h p le n t y o f w a t e r f o r a t le a s t 1 5 m in u t e s w h ile r e m o v in g c o n t a m in a t e d c lo th in g a n d s h o e s .
W a s h c lo th in g b e fo r e r e u s e .
T h o r o u g h ly c le a n s h o e s b e fo r e r e u s e .
G e t m e d ic a l a tte n tio n
immediately.
Inhalation
If t h e v ic t im is n o t b r e a t h in g , p e r f o r m m o u t h - t o - m o u t h r e s u s c it a t io n . L o o s e n t ig h t c lo t h in g s u c h a s a c o lla r , t ie , b e lt o r w a is t b a n d .
If b r e a t h in g is d if f ic u lt , o x y g e n c a n b e a d m in is t e r e d .
S e e k m e d ic a l a t t e n t io n if r e s p ir a t io n p r o b le m s d o n o t
improve.
Ingestion
IN D U C E V O M IT IN G b y s t ic k in g f in g e r in t h r o a t .
L o w e r t h e h e a d s o t h a t t h e v o m it w ill n o t r e e n t e r t h e m o u t h a n d t h r o a t .
L o o s e n t ig h t c lo t h in g s u c h a s a c o lla r , t ie , b e lt o r w a is t b a n d . r e s u s c it a t io n .
If t h e v ic t im is n o t b r e a t h in g , p e r f o r m m o u t h - t o - m o u t h
E x a m in e t h e lip s a n d m o u t h t o a s c e r t a in w h e t h e r t h e t is s u e s a r e d a m a g e d , a p o s s ib le in d ic a t io n t h a t t h e
toxic material was ingested; the absence of such signs, however, is not conclusive.
Section V. Flammability Flash Points Combustion Products Fire Hazards Explosion Hazards
Fire and Explosion Data Auto-Ignition
Not available.
Flammable Limits
Not available.
May be combustible at high temperature. Not available.
These products are toxic carbon oxides (CO, CO
2
), sulfur oxides (SO
2
, SO 3 ...), nitrogen oxides (NO
x
).
Not available.
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Consult with local fire authorities before attempting large scale fire-fighting operations.
Continued on Next Page Printed 1/3/2007.
Emergency phone number
(800) 424-9300
D0782 Section VI. Spill Cleanup Instructions
N,N-Dimethyl-1,4-phenylenediamine Sulfate
Page 2
Accidental Release Measures Toxic Material. Irritating Material. Light Sensitive Material. S t o p le a k if w it h o u t r is k . D O N O T g e t w a t e r in s id e c o n t a in e r . D O N O T t o u c h s p ille d m a t e r ia l. U s e w a t e r s p r a y t o r e d u c e vap o rs.
P r e v e n t e n t r y in t o s e w e r s , b a s e m e n t s o r c o n f in e d a r e a s ; d ik e if n e e d e d .
E lim in a t e a ll s o u r c e s o f ig n it io n .
Consult federal, state, and/or local authorities for assistance on disposal.
Section VII. Handling and Storage Information
Handling and Storage T O X IC .
IR R IT A N T .
L IG H T S E N S IT IV E .
R E F R IG E R A T E .
K e e p lo c k e d u p ..
K eep a w a y fro m h ea t.
r e q u ir e d . W h e n n o t in u s e , t ig h t ly s e a l t h e c o n t a in e r a n d s t o r e in a d r y , c o o l p la c e . N O T in g e s t .
D o n o t b re a th e d u s t.
W e a r s u it a b le p r o t e c t iv e c lo t h in g .
M e c h a n ic a l e x h a u s t
A v o id e x c e s s iv e h e a t a n d lig h t . D O
If in g e s t e d , s e e k m e d ic a l a d v ic e im m e d ia t e ly a n d
show the container or the label. Treat symptomatically and supportively. Always store away from incompatible compounds such as oxidizing agents, acids.
Section VIII. Engineering Controls
Exposure Controls/Personal Protection U s e p r o c e s s e n c lo s u r e s , lo c a l e x h a u s t v e n tila tio n , o r o th e r e n g in e e r in g c o n tr o ls to k e e p a ir b o r n e le v e ls b e lo w r e c o m m e n d e d e x p o s u r e lim it s .
If u s e r o p e r a t io n s g e n e r a t e d u s t , f u m e o r m is t , u s e v e n t ila t io n t o k e e p e x p o s u r e t o
airborne contaminants below the exposure limit.
Personal Protection
S p la s h g o g g le s .
L a b c o a t.
D u s t r e s p ir a t o r .
in h a la t io n o f t h e p r o d u c t .
B o o ts .
G lo v e s .
A M S H A / N IO S H a p p r o v e d r e s p ir a t o r m u s t b e u s e d t o a v o id
S u g g e s t e d p r o t e c t iv e c lo t h in g m ig h t n o t b e s u f f ic ie n t ; c o n s u lt a s p e c ia lis t B E F O R E h a n d lin g
this product.
Exposure Limits
Section IX. Physical state @ 20°C Specific Gravity Molecular Weight
Not available.
Physical and Chemical Properties
Partition Coefficient
234.27
495°C (923°F)
Melting Point
200 to 205°C (392 to 401°F)
Critical Temperature Viscosity
Section X. Stability Conditions of Instability Incompatibilities
Section XI. RTECS Number Routes of Exposure Toxicity Data
Not available.
Vapor Pressure
Not applicable.
Vapor Density
Not available.
Not available.
Volatility
Not available.
Not available.
Odor
Not available.
Not available.
Taste
Not available.
(Dec)
Stability and Reactivity Data This material is stable if stored under proper conditions. (See Section VII for instructions) Avoid excessive heat and light. Reactive with strong oxidizing agents, acids, acid chlories, acid anhydrides, chloroformaets.
Toxicological Information ST1575000
Eye Contact. Ingestion. Inhalation.
Rat LD Rat LDL
50 o
Mouse LD
Chronic Toxic Effects
Soluble in water.
Not available.
Boiling Point
Refractive Index
Solubility
Solid. (White Crystalline Powder.)
(oral) 100 mg/kg (oral) 75 mg/kg 50
(oral) 59 mg/kg
CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY : Not available. R e p e a t e d e x p o s u r e t o a n h ig h ly t o x ic m a t e r ia l m a y p r o d u c e g e n e r a l d e t e r io r a t io n o f h e a lt h b y a n a c c u m u la t io n in o n e o r many human organs.
Acute Toxic Effects
T o x ic if in g e s t e d o r in h a le d .
A v o id p r o lo n g e d c o n t a c t w it h t h is m a t e r ia l.
O v e r e x p o s u r e m a y r e s u lt in s e r io u s illn e s s o r
death. Ir r it a t in g t o e y e s a n d s k in o n c o n t a c t .
In h a la t io n c a u s e s ir r it a t io n o f t h e lu n g s a n d r e s p ir a t o r y s y s t e m .
t h e e y e is c h a r a c t e r iz e d b y r e d n e s s , w a t e r in g , a n d it c h in g .
In f la m m a t io n o f
S k in in f la m m a t io n is c h a r a c t e r iz e d b y it c h in g , s c a lin g ,
reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Continued on Next Page Printed 1/3/2007.
Emergency phone number
(800) 424-9300
D0782 Section XII.
N,N-Dimethyl-1,4-phenylenediamine Sulfate Ecological Information
Ecotoxicity
Not available.
Environmental Fate
Not available.
Section XIII. Waste Disposal
Page 3
Disposal Considerations R e c y c le t o p r o c e s s , if p o s s ib le . C o n s u lt y o u r lo c a l r e g io n a l a u t h o r it ie s . Y o u m a y b e a b le t o d is s o lv e o r m ix m a t e r ia l w it h a c o m b u s t ib le s o lv e n t a n d b u r n in a c h e m ic a l in c in e r a t o r e q u ip p e d w it h a n a f t e r b u r n e r a n d s c r u b b e r s y s t e m . O b s e r v e a ll federal, state and local regulations when disposing of the substance.
Section XIV. DOT Classification PIN Number Proper Shipping Name Packing Group (PG)
Transport Information DOT Class 6.1: Toxic material.
UN2811
Toxic solid, organic, n.o.s.
III
DOT Pictograms
Section XV. TSCA Chemical Inventory (EPA) WHMIS Classification (Canada) EINECS Number (EEC) EEC Risk Statements
Other Regulatory Information and Pictograms This compound is
ON the EPA Toxic Substances Control Act (TSCA) inventory list.
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). On DSL. 208-636-2 R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin.
Japanese Regulatory Data
Section XVI.
ENCS No. (3)-243
Other Information
Version 1.0 Validated on 1/3/2007. Printed 1/3/2007. Notice to Reader TCI laboratory chemicals are for research purposes only and are NOT intended for use as drugs, food additives, households, or pesticides. The information herein is believed to be correct, but does not claim to be all inclusive and should be used only as a guide. Neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All chemical reagents must be handled with the recognition that their chemical, physiological, toxicological, and hazardous properties have not been fully investigated or determined. All chemical reagents should be handled only by individuals who are familiar with their potential hazards and who have been fully trained in proper safety, laboratory, and chemical handling procedures. Although certain hazards are described herein, we can not guarantee that these are the only hazards which exist. Our MSDS sheets are based only on data available at the time of shipping and are subject to change without notice as new information is obtained. Avoid long storage periods since the product is subject to degradation with age and may become more dangerous or hazardous. It is the responsibility of the user to request updated MSDS sheets for products that are stored for extended periods. Disposal of unused product must be undertaken by qualified personnel who are knowledgeable in all applicable regulations and follow all pertinent safety precautions including the use of appropriate protective equipment (e.g. protective goggles, protective clothing, breathing equipment, facial mask, fume hood). For proper handling and disposal, always comply with federal, state, and local regulations. Printed 1/3/2007.
